Change Send/Receive Message Size Limits Exchange 2010

You will need to change these settings on few places as below;

Global Settings
Organization Configuration->Hub Transport->Global Settings->Properties of Transport Settings
Here you can adjust your transport send/receive limits.

Send Connector
Organization Configuration->Hub Transport->Send Connectors->Properties of Default Send
Here you can adjust your send connectors default maximum message size

Receive Connector
Server Configuration->Hub Transport->Receive Connectors Pane->Properties of Default <hostname>
Here you can adjust your receive connectors default maximum message size

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